"A
Nanostructured Gas Sensor: Coupling a Selective Molecular Level Event to an
External Circuit"
In this project, we are trying to make a new type of gas sensor
with direct electrical readout using a Au nanocluster array with selective
molecular linkers.
The macroscopic contact pads
consist of interdigited Au finger patterns with various spacings formed on a
SiO2 surface with conventional UV lithography, e-beam
evaporation, and liftoff. To enhance the contact continuity between the
cluster film and the Au fingers, thin metallization (10 nm) is used. Thicker
Au layers are used on the probe pads for stable probing. High quality
monolayer arrays of either 5 nm diameter or 10 nm diameter Au clusters, that
are encapsulated by alkanethiol molecules, are formed on a water surface and
picked up by a flat elastomeric pad of polydimethylsiloxane. The arrays are
subsequently transferred to the contact pad structures by stamping. The
procedure is repeated a second time in order to form a cluster bilayer on
the substrate. A bilayer provides a more flexible structure for
intercluster linking.
We are
currently in the process of inserting porphyrin molecules as intercluster
linkers. It is expected that the substitution of various metal atoms in the
porphyrins will provide selective docking, and therefore selective
recognition of various gas species. This structure has the potential to
provide selective and highly sensitive gas sensing, and can be easily
integrated with CMOS control circuitry.